HS-400

HS-400 Safety Data Sheet

Revision date : 2020

 

Section 1: Product and Company Information


 

Product Name Product Type Company ID Emergency
Phone Number
Address Common Use
of Product
HS-400 Activated Alumnia Hydrosil International Ltd. 847-844-0680 125 Prairie Lake Rd.
East Dundee, IL 60018
Filtration

Section 2: Hazard(s) Identification


OSHA Regulatory Status: Not Regulated

Health Effects: Prolonged over exposure to dust can produce skin and eye irritation

2.1 – Classification of the substance or mixture (GHS-US)

Pictogram Signal Word  Hazard Statement
Warning Eye Irritation 2B H320; Acute Oral Tox 4, H302; Respiratory Irritation H335
Oxidizer The material is not combustible. This material contains an oxidizing substance (potassium permanganate).The material is considered to have no oxidizing properties that should be classified as “not oxidizing” and “Not a Division 5.1” following UN Handbook. Ox. Sol. 2, H272

2.2 – Precautionary statements (GHS-US) :

P210 – Keep away from heat/sparks/open flames/hot surfaces. – No smoking
P220 – Keep/Store away from clothing/combustible materials
P221 – Take any precaution to avoid mixing with combustibles
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear protective gloves/protective clothing/eye protection/face protection
P304+P340 – IF INHALED: Remove person to fresh air and keep comfortable for breathing
P312 – Call a POISON CENTER/doctor if you feel unwell
P370+P378 – In case of fire: Use for extinction
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P405 – Store locked up
P501 – Dispose of contents/container

2.3 – Other Hazards

No additional information available

2.4 – Unknown acute toxicity (GHS US)

No data available

 

Section 3: Composition/Information on Ingredients


 

Name Product Identifier Percent By Weight (%) GHS-US Classification
Activated Alumnia (CAS No.) 1333-84-2 79.5-81.5 STOT SE 3, H335
Water (CAS No.) 7732-18-5 12.5-14.5 Not Classified
Potassium Permanganate (CAS No.) 7722-64-7 4 Ox. Sol. 2, H272
Acute Tox. 4 (Oral), H302

Section 4: First-Aid Measures


4.1 – Description of first aid measures

Inhalation
First Aid            
Remove person to fresh air. If not breathing, administer CPR or artificial respiration. Get immediate medical attention.
Skin Contact
First Aid
If skin reddening or irritation develops, seek medical attention.
Eye Contact
First Aid
Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists get medical attention.
Ingestion
First Aid
If the material is swallowed, get immediate medical attention or advice. DO NOT induce vomiting unless directed to do so by medical personnel.

4.2 – Most important symptoms and effects, both acute and delayed

Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes eye irritation.
Symptoms/injuries after ingestion : May be harmful if swallowed.

4.3 – Indication of any immediate medical attention and special treatment needed

No additional information available

 

Section 5: Fire-Fighting Measures


5.1 – Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2 – Special hazards arising from the substance or mixture

The mixture is not combustible. This material contains an oxidizing substance (potassium permanganate). The material is considered to have no oxidizing properties that should be classified as “not oxidizing” and “Not a Division 5.1” following United Nations (UN) Handbook.  Testing 34.4.1 confirms that this material is not a Division 5.1 material.

5.3 – Advice for firefighters

Protection during firefighting : Firefighters should wear full protective gear (chemical protective clothing and breathing apparatus).

 

Section 6: Accidental Release Measures


6.1 – Personal precautions, protective equipment and emergency procedures

General measures : Avoid contact with the skin and the eyes.
For non-emergency personnel : No additional information available
For emergency responders : No additional information available

6.2 – Environmental precautions

Do not allow material to enter surface water or drains. If the material contacts water, the potassium permanganate may leach out and turn the water a pink/purple color.

6.3 – Methods and material for containment and cleaning up

For containment : If possible, stop flow of product.
Methods for cleaning up : Shovel or sweep up and put in a closed container for disposal.

6.4 – Reference to other sections

No additional information available

 

Section 7: Handling and Storage


7.1 – Precautions for safe handling

Avoid generation of dust.

7.2 – Conditions for safe storage, including any incompatibilities

Storage conditions : Protect containers from physical damage. Keep container tightly closed and store in dry, cool, well-ventilated area. Protect material from water and contaminated gases.

7.3 – Specific end use(s)

No additional information available

 

Section 8: Exposure Controls/Personal Protection


8.1 – Control parameters

No additional information available

8.2 – Exposure controls/Person Protection

Appropriate engineering controls : Local exhaust and general ventilation must be adequate to meet exposure standards.
Hand protection : Use impervious gloves to minimize skin contact.
Eye protection : Safety glasses.
Skin and body protection : Wear suitable working clothes.
Respiratory protection : If airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection.

 

Section 9: Physical and Chemical Properties


9.1 – Information on basic physical and chemical properties

Physical state : Solid
Appearance : Granules
Colour : Purple
Odour : No data available
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Self ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : 59-61 lb/ft3
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available

Section 10: Stability and Reactivity


10.1 – Reactivity

Contact with strong oxidizers such as ozone, liquid oxygen, chlorine, etc. may result in fire.

10.2 – Chemical stability

Stable under normal conditions.

10.3 – Possibility of hazardous reactions

May occur with contact of acids or strong oxidizing agents.

10.4 – Conditions to avoid

Liquid water. Heat sources, open flames, or other ignition sources.

10.5 – Incompatible materials

Strong oxidizers or acids.

10.6 – Hazardous decomposition products

None.

 

Section 11: Toxicological Information


11.1 – Information on toxicological effects

Acute toxicity : Not classified

Aluminium Oxide (CAS No. 1344-28-1)
LD50 Oral Rat  >2000 mg/kg
LC50 Inhalation Rat 0.888 (Exposure Time: 4 Hr)

 

Potassium Permanganate(CAS No. 7722-64-7)
LD50 Oral Rat 750 mg/kg

Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified

Section 12: Ecological Information


12.1 – Toxicity

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Potassium Permanganate (CAS No. 7722-64-7)
LC50 Fishes 1 3.3 – 3.93 mg/l (Exposure time: 96 h – Species: Carassius auratus [static])
LC50 Fish 2 2.97 – 3.11 mg/l (Exposure time: 96 h – Species: Cyprinus carpio)

12.2 – Persistence and degradability

No additional information available

12.3 – Bioaccumulative potential

Potassium Hydroxide (CAS No. 1310-58-3) Log Pow: 0.65

12.4 – Mobility in soil

No additional information available

12.5 – Other adverse effects

No additional information available

 

Section 13: Disposal Considerations


13.1 – Waste treatment methods

Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations.

Section 14: Transport Information


In accordance with DOT / ADR / RID / ADNR / IMDG / ICAO / IATA

14.1 – UN number

Not applicable

14.2 – UN proper shipping name

Not applicable

Section 15: Regulatory Information


All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.

15.1 – US Federal regulations

This product is not known to be a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
– Classification and labelling information included in section 2:

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D): Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4): Not listed.
SARA 304 Emergency release notification: Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories

 Potassium Permanganate (CAS No. 7722-64-7)
Reportable Quantity, Section 304 of EPA’s List of Lists: 100 pounds

15.2 – US State regulations

Review specific state regulations.

Potassium Permanganate (CAS No. 7722-64-7)
U.S. – Massachusetts – Right To Know (RTK) List
U.S. – New Jersey – RTK Hazardous Substance List
U.S. – Pennsylvania – RTK List

Section 16: Other Information


Full text of H-phrases:

Eye Dam. 1 Serious eye damage/eye irritation Category 1
Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
Skin Corr. 1A Skin corrosion/irritation Category 1A
Skin Irrit. 2 Skin corrosion/irritation Category 2
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H319 Causes serious eye irritation
Ox. Sol 2 Oxidising Solids, Category 2

NFPA health hazard : 1 – Exposure could cause irritation but only minor residual injury even if no treatment is given.
NFPA fire hazard : 0 – Must be preheated before ignition can occur.
NFPA reactivity : 0 – Normally stable, even under fire exposure conditions, and are not reactive with water

 

Copyright 2020 Hydrosil International, LTD. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. Hydrosil International LTD. makes no warranty, either expressed or implied, including any warranties of merchantability and fitness for a particular purpose.

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